Annie Chemie P Ltd. India Annie Chemie P Ltd, is a company at Dahej in Gujarat, India. It is a manufacturer exporter of Calcium Propionate & Sodium Propionate and oil field shale gas fracking or hydraulic fracturing chemicals and speciality chemicals and it has substantial exports to countries like USA, Canada, UK, Europe, UAE, Nigeria, Algeria, Turkey, Mexico, Brazil, Chile, Argentina, Australia, Kuwait, Dubai etc. We have developed encapsulated guar gel breaker based on coated ammonium persulfate, potassium persulfate, sodium persulfate, potassium peroxymonopersulfate, sodium bromate etc. We also supply other coated or encapsulated products like citric acid, guar crosslinkers other shale gas frac related products like diverting agent, KCl-substitute or clay-stabilizer, corossion inhibitors, scale inhibitor, bio-guard and several speciality chemicals.

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Calcium Propionate SDS of Suppliers Exporters, Manufacturers

Calcium Propionate
CAS Number: 4075-81-4 USP NF FCC Food Grade Suppliers Exporters, Manufacturers
Calcium Propionate Manufacturers Exporters

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Calcium propionate or Calcium dipropionate or Propionic acid calcium salt
SDS, Safety Data Sheet
MSDS Sheet
13-May-22

1. Product Identification

Product Name & Other Names: Calcium propionate or Propionic acid, calcium salt or Calcium dipropionate.
CAS No.: 4075-81-4
EINECS, EC Number: 223-795-8
Relevant uses and uses advised against (if any): Laboratory and Industrial Manufacturing.
SUPPLIER: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

3. Composition/Information on Ingredients

Product Name & Other Names: Calcium propionate or Propionic acid, calcium salt or Calcium dipropionate.
CAS No.: 4075-81-4
EINECS, EC Number: 223-795-8

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: May be combustible at elevated temperature.
Products of Combustion: Fumes, Calcium Oxide Carbon dioxide & Carbon Monoxide.
Explosion: Slightly explosive on heating.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At elevated temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. On decomposition it may emit carbon monoxide. Containers may explode on heating.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing agents.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not Specified.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Appearance: Colorless or white powder or crystals.
Odor: It is odorless.
Odor threshold: Not applicable.
pH: No data found.
Relative density: around 3.13
Melting Point: 681C 1257F
Initial boiling point and boiling range
: No data found.
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: It is soluble in water.
Viscosity: No data found.
Molecular formula: (CH3CH2COO)2Ca
Molecular weight: 186.2

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon monoxide & fumes when heated to decomposition. It may form calcium oxide harmful gases.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Incompatibles and moisture.

11. Toxicological Information

Toxicity data
ORL-RAT LD50 3290 mg kg-1
ORL-MAM LD50 2350 mg kg-1
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: No data found.
Teratogenic Effects: No data found.
Developmental Toxicity: No data found.

12. Ecological Information

Environmental Fate: Not classified as environmentally hazardous.
Environmental Toxicity: This chemical is expected to cause little oxygen depletion in aquatic systems.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
Toxicity of the Products of Biodegradation: The products of degradation and the product are not classed as toxic.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
IMO/IMDG: Not controlled.
IATA/ICAO: Not controlled.

15. Regulatory Information

SARA 311/312 Hazards: Not Listed.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Section 16 - Additional Information

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.

Calcium Propionate Suppliers

Please visit Technical Data Sheet of Calcium Propionate USP NF FCC Food Grade Suppliers.

Calcium Propionate CAS Number 4075-81-4 & Sodium Propionate CAS Number 137-40-6 & 6700-17-0 Supplier Exporter, Manufacturer:

Annie Chemie P Ltd
Mumbai 4000010, INDIA
With Agents and offices in UAE, USA, Europe.

e-mail: info@anniechemie.com

Copyright and Usual Disclaimer is Applicable.
September 27, 2023

Exporters to USA, Canada, UK, Europe, UAE, Nigeria, Algeria, Turkey, Mexico, Brazil, Chile, Argentina, Australia, Dubai etc.

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