Sodium Sulfide Nonahydrate SDS of Manufacturer Exporter

Annie Chemie P Ltd, is a company at Dahej in Gujarat, India. It is a manufacturer exporter of Sodium Sulfide Nonahydrate & Sodium Sulfate and oil field shale gas fracking or hydraulic fracturing chemicals and speciality chemicals and it has substantial exports to countries like USA, Canada, UK, Europe, UAE, Nigeria, Algeria, Turkey, Mexico, Brazil, Chile, Argentina, Australia, Kuwait, Dubai etc. We have developed encapsulated guar gel breaker based on coated ammonium persulfate, potassium persulfate, sodium persulfate, potassium peroxymonopersulfate, sodium bromate etc. We also supply other coated or encapsulated products like citric acid, guar crosslinkers other shale gas frac related products like diverting agent, KCl-substitute or clay-stabilizer, corossion inhibitors, scale inhibitor, bio-guard and several speciality chemicals.

Sodium Sulfide Nonahydrate SDS Suppliers Exporters, Manufacturers

Sodium Sulfide Nonahydrate
CAS Number: 1313-84-4 for Nonahydrate & 1313-82-2 USP Reagent Grade for Anhydrous Suppliers Exporters, Manufacturers
Sodium Sulfide Nonahydrate Manufacturers Exporters

Sodium Sulfide Nonahydrate Manufacturers Exporters

Product Name & Other Names: Sodium Sulfide Nonahydrate or Sodium monosulfide nonahydrate or Sodium sulphide nonahydrate.
CAS No.: 1313-84-4
EINECS EC-No.: 215-211-5
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4) H302
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Category 1B) H314
Acute aquatic toxicity (Category 1) H400

Hazard statements:
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.

Product Name & Other Names: Sodium Sulfide Nonahydrate or Sodium monosulfide nonahydrate or Sodium sulphide nonahydrate.
CAS No.: 1313-84-4
EINECS EC-No.: 215-211-5

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Non-flammable.
Products of Combustion: Sulphur oxides, Sodium oxides, fumes.
Fire: Sodium Sulfide Nonahydrate is not considered to be a fire hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use water to cool fire-exposed containers.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. On decomposition it may emit hydrogen sulfide. Containers may explode on heating.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Corrosive solid. Avoid touching the spilled material. Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Do not ingest. Do not breathe dust. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing agents, metals, acids.

Airborne Exposure Limits: Not established for the product. However, if Hydrogen sulfide is released in handling and use, then observe its limits.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.

Appearance: Yellowish powder.
Odor: rotten egg-like.
Odor threshold: Not available.
pH: Alkaline
Relative density: around 1.43
Boiling Point: 920C - lit.
Melting Point: 50C.
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: It soluble in water.
Viscosity: No data found.
Molecular Weight: 240.18
Chemical Formula: Na2S-9H20

Stability: Stable under ordinary conditions of use and storage. One can say it is moderately stable in atmospheric condition. Aqueous solutions and moist solid may slowly give off hydrogen sulfide gas. Air and light sensitive. May discolor on exposure to air. Liberates toxic hydrogen sulfide on contact with acids. Reacts violently with carbon, diazonium salts; n,n-dichloromethylamine, o-Nitroaniline, diazonium salt, water. Reacts with water to form strong solutions and Hydrogen sulfide Reacts with acid more vigorously , producing corrosive solutions, and hydrogen sulfide. Also incompatible with Acids, Aluminum, Zinc. Decomposes in air at 920-950 deg. C.
Hazardous Decomposition Products: It emits toxic hydrogen sulfide fumes when heated to decomposition. It may form sodium oxide and sulfur.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, metals & acids.
Conditions to Avoid: Incompatibles and moisture.

Toxicity data
Oral LD50 Mouse: 205 mg/kg
Oral LD50 Rat: 208 mg/kg; Intraperitoneal LD50 147 mg/kg
LD50 Dermal: < 340 mg/kg ( Rabbit )
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: No data found.
Teratogenic Effects: No data found.
Developmental Toxicity: No data found.

Toxicity to fish: LC50: 7.7 - 29.1 mg/L, 96h (Poecilia reticulata) for Na2S
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED
IMDG/IMO:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED
ICAO/IATA:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED.

USA:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Sodium Sulfide Nonahydrate CAS Number 1313-84-4 for Nonahydrate & 1313-82-2 for Anhydrous & Sodium Sulfate Decahydrate Anhydrous CAS Number 7757-82-6 for anhydrous and 7727-73-3 for decahydrate Supplier Exporter, Manufacturer:

Annie Chemie P Ltd
Mumbai 4000010, INDIA
With Agents and offices in UAE, USA, Europe.

Exporters to USA, Canada, UK, Europe, UAE, Nigeria, Algeria, Turkey, Mexico, Brazil, Chile, Argentina, Australia, Dubai etc.